【摘 要】
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The highest experimentally known oxidation state of lanthanide has long been determined to be Tb(Ⅳ).Here we report a combined matrix-isolation infrared spectroscopic and theoretical study of two inter
【机 构】
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Department of Chemistry & Key Laboratory of Organic Optoeletronics and Molecular Engineering of the
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The highest experimentally known oxidation state of lanthanide has long been determined to be Tb(Ⅳ).Here we report a combined matrix-isolation infrared spectroscopic and theoretical study of two interconvertible terbium tetra-oxide complexes:a C2v-structure peroxide complex(O2-)TbO2+and a(O2)TbO2 vdw-complex,which are formed by co-condensation of laser-ablated iron atoms and electrons with O2/Armixtures at 4 K.
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