【摘 要】
：
Transfer hydrogenation of aliphatic ketones catalyzed by water-soluble ruthenium complex, [RuC12(TPPTS)2] (TPPTS=P(m-C6H4SO3Na)3), in the presence of surfactant
【机 构】
：
CollegeofBiol.,Chem.Sci.andEngn.,JiaxingUniversity,Jiaxing,314001
论文部分内容阅读
Transfer hydrogenation of aliphatic ketones catalyzed by water-soluble ruthenium complex, [RuC12(TPPTS)2] (TPPTS=P(m-C6H4SO3Na)3), in the presence of surfactants, was investigated[1,2].Our results showed that the conversion was dramatically enhanced by cationic surfactants.Compared to a single long-chain surfactant, a double long-chain cationic surfactant has more profound effect on the reaction.Most of all, when the length of alkyl chain of substrate matched with that of the surfactant, the conversion rote increased significantly.
其他文献
The synthesized structures of supported and separate Au nanoparticles (NPs) are unstable and tend to grow at high temperatures,leading to the deactivation.Core-
Here we review some recent progresses in our laboratory related to the hydrothermal synthesis of metal oxides/hydroxides and metal chalcogenides nanoarrays, who
Phenol is widely used in industry as an important chemical.It is mainly manufactured by a three-step cumene process, which features many disadvantages such as l
A new crystallized Cu(Ⅱ) complex with conjugated, rigid and planar salen-type ligand has been studied, which exhibits an unusual fluorescent selectivity for di
Stimuli-responsive color-changing materials have attracted much attention for studying the intrinsic reaction mechanism and their potential applications in opto
In the past decades, microporous metal-organic frameworks (MMOFs) have been proven as promising materials for revolutionizing industrial applications, such as s
PhIO is a common hypervalent iodine compound1 and plays an important role in the oxidation of hydrocarbons under the catalysis of transition metal complexes2.It
Carbon monoxide (CO) is believed to be an essential signaling molecule like nitric oxide (NO).1 It can play important physiological role in human body, for exam
The chemistry of metal-organic frameworks (MOFs)1 by inorganic units and organic struts are well established in many groups nowadays.Extensive research has been
[FeFe]-hydrogenase is one of a class of remarkably efficient enzymes for both catalytic evolution and oxidation of H2.Tremendous synthetic and spectroscopic wor