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Solvothermal reaction of Manganese(Ⅱ)salt with monosodium 2-sulfoterephthalate(2-NaH2stp)and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp)2(bpp)2(H2O)4](1)and [Mn3(stp)2(tpy)3(H2O)](H2O)5(2)(bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline,tpy = 2,2:6,2-Terpyridine).