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Based on the facially polarized all-cis 1,2,3,4,5,6-hexafluorocyclohexane(1),[1,2] a new kind of excess electron compounds,namely M+-1-M-(M = Li,Na,and K; M = Cu,Ag,and Au) were designed and investigated in this work.These compounds are the first examples of organometallic salts wherein the coinage metal atoms occupy the anionic sites,and thus termed coinage metalides.