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  5. Mechanistic insight into the high stereoselectivity of Co(Ⅲ)-catalyzed three-component C-H addition

Mechanistic insight into the high stereoselectivity of Co(Ⅲ)-catalyzed three-component C-H addition

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户：h482649
【摘 要】
：
A three-component C(sp2)-H bond addition across alkene and polari zed π-bonds wi th high stereoselectivity was repor ted for which Cp*CoⅢ catalysis was shown to be much more effect ive than Cp*RhⅢ.
【作 者】
：
Xuexiang Ma Jianbiao Liu Fang Huang Chuanzhi Sun DezhanChen 
【机 构】
：
Col lege of Chemist ry,Chemical Engineering and Material s Science,Collaborat ive Innova tion Center
【出 处】
：
第十三届全国量子化学会议
【发表日期】
：
2017年10期
【关键词】
：
high stereoselectivity three-component C-H funct ionalization 
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　　A three-component C(sp2)-H bond addition across alkene and polari zed π-bonds wi th high stereoselectivity was repor ted for which Cp*CoⅢ catalysis was shown to be much more effect ive than Cp*RhⅢ.
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