【摘 要】
:
Metal-Organic Frameworks (MOFs) with magnetic property have always drawn great attractions.1 Here we report a series of Cu-MOFs constructed from 1,1-[1,4-phenylene-bis-(methylene)]bis(4,4-bipyridinium
【机 构】
:
State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter
论文部分内容阅读
Metal-Organic Frameworks (MOFs) with magnetic property have always drawn great attractions.1 Here we report a series of Cu-MOFs constructed from 1,1-[1,4-phenylene-bis-(methylene)]bis(4,4-bipyridinium) dichloride (L·Cl2) and isophthalic acid (ipt) with different substituent groups,namely [Cu4(OH)2(L)(CH3-ipt)4] (1), [Cu2(OH)(L)0.5(CH3-ipt)2]·2H2O (2) and [Cu2(OH)(L)0.5(NO2-ipt)2] (3).
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