The chemistry of metal-metal-bonded compounds with low-coordinate,low-valent metal ions has attracted much attention owing to their novel structures and reactivity towards small molecules,which often
The novel four-coordinate manganese organic-inorganic hybrid crown ether clathrate,[H2en-(18-crown-6)2]2+[MnCl4]2-(1)(en= ethanediamine),has been prepared via hydrothermal reaction.
The lanthanide-based SMMs are attracting the growing attentions due to the intrinsic strong spin-orbital coupling and magnetic anisotropy of lanthanide(Ⅲ)ions[1].
Single-molecular magnets(SMMs)have been of great interest in the field of molecular magnetic materials since the discovery of the Mn12-Ac SMM at the beginning of the 1990s,Besides their theoretical in