Long-term Performance of Zeolite Membrane for Produced Water Purification

来源 :2011全国非常规水源利用技术研讨会 | 被引量 : 0次 | 上传用户:chenlm08
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Water produced from hydrocarbon-bearing formations during oil and gas industry operations contains a high concentration of ions or dissolved solids.Desalination of such water is an attractive option for providing potable water in arid or semi-arid regions.However,oilfield brine desalination is not economical at this time because of the high total dissolved solids (TDS) content that can reduce the efficacy of reverse osmosis (RO).In this paper,we report a novel technology of using a zeolite membrane for reclamation of produced water,based on RO.Zeolites are microporous aluminosilicate materials with extremely uniform pores defined by crystal structures.Their extremely stable chemical,mechanical and thermal properties render zeolite membranes suitable for difficult separations such as high ion concentration,a strong solvent environment,or those requiring high temperatures and high pressures.A MFI zeolite membrane was synthesized on the inner surface of α- alumina tunable substrate by two-step crystallization.The thickness of the membrane was measured as ~2.0 μm.Produced water with TDS of 2.17 × 104 mg/L and total dissolved organics of 329.2 mg/L was used for the RO test.The test was performed at room temperature under a transmembrane pressure of 3.5MPa.It was observed that the synthesized membrane had Na+ rejection of 98%,Ca2-/Mg2+ rejection of 100%,dissolved organics rejection of 95%,and water flux of 1.3 kg/m2.h.A long-term RO test was carried out,under the transmembrane pressure of 3.5MPa,for more than two months.Both water flux and ion/organics rejection were recorded every 24 hr.It was found that the water flux decreased and leveled off at 0.35 kg/m2.h after 35 days.Ions and organic rejections decreased to 40% and 50%,respectively.Further studies including scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS) revealed that CaCO3 deposited on the membrane surface.
其他文献
消毒剂杀灭真菌效果比较吴立成(湖北省荆州地区卫生学校江陵434100)为了解消毒剂对真菌的杀灭作用,我们以戊二醛、碘伏、乙醇、来苏儿、84消毒液(含次氯酸钠与表面活性剂)、新洁尔灭等消毒
目的 建立X射线荧光光谱法测定面粉、糖果、果冻、鱼丸等食品中二氧化钛的快速检测方法 .方法 针对不同的食品形态,分别探究干燥后粉碎、加入稀释剂粉碎、均质、加稀释剂均质
因初中的信息技术课不纳入考试范围,所以学校对于学生信息技术的重视程度也没有其他科目那么高,导致信息技术课的排课率减少,大部分学校安排的都是一周只有一节信息技术课,从
  肾移植术后结石并发症的发生率很低,相关文献报道也很少。本文对肾移植术后结石诊断和治疗的临床经验进行了总结,目的是减少肾移植术后结石并发症,延长移植肾存活时间。研究
目的 采用3种方法 对鸡肉粉中沙门氏菌进行检测.方法 3份样品的前处理依据组织方提供的《作业指导书》进行,每瓶样品直接加入4.5 mL灭菌去离子水复溶,作为初始样本,后续实验
电力用户最关心的问题就是用电报装提速.原本的低压报装模式中并未有统一的时限以及规范管理程序,各个供电所之间也存在明显的差别.这导致了业扩报装工作停滞不前,无法得到更
当前社会,随着我国城市化进程和工业生产的飞速发展,电力能源产业与我们每个人工作和生活都密不可分,对电力企业的发展也带来了良好的发展机遇,但也必须意识到,随着国家政策
有定期存单(折)的人们在急于用现金时,往往到银行办理小额质押贷款,但很多人对此还存在认识误区。如果能合理搭配贷款期限,不仅小有“赚头”,而且能更充分地享受贷款便利。技
Seawater desalination has emerged as an important source of fresh water.Low-temperature multi-effect distillation (LT-MED) is one of main methods of seawater de
  本文通过对应用亚胺培南/西司他汀钠(泰能)治疗肾移植术后重症肺部感染患者过程中发生的精神系统的不良反应进行分析,进而探讨泰能在治疗肾移植术后重症肺部感染中的作用