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A near infrared(NIR)light responsive chromophore 7-(diethylamino)-4-(hydroxymethyl)-2H-chromen-2-one(DEACM)was synthesized and incorporated to β-cyclodextrins with cRGD functionalized poly(ethylene glycol),the amphiphiles were coordinated with Au nanorods or Au nanoparticles to load anticancer drug doxorubicin(DOX)and fabricate hybrid nanoparticles for synergistic cancer therapy.