【摘 要】
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Catalytic functionalization of amines by direct C-H activation has attracted much attention in organic chemistry in recent years, because functionalized amines are versatile intermediates and have bee
【机 构】
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Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Phys
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Catalytic functionalization of amines by direct C-H activation has attracted much attention in organic chemistry in recent years, because functionalized amines are versatile intermediates and have been widely used in the construction of biologically active compounds and functional materials.In the present work, we wish to report theα-alkylation of secondary amines, by combining visible light catalysis and transition metal catalysis, where molecular oxygen used as terminal oxidant, up to 93％ yield of cross-coupling products were achieved under blue LEDs irradiation for 12 h.
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