Transition-Metal-Catalyzed Carbene Coupling Reaction:Methodology Development and Theoretical Studies

来源 :中国化学会第八届全国配位化学会议 | 被引量 : 0次 | 上传用户:heruoss
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  In this presentation,several novel cross-coupling processes based on migratory insertion of metal carbene are discussed.These coupling reactions demonstrate new possibilities of carbenebased process in the development of novel transition-metal-catalyzed C-C bond forming reaction.
其他文献
Copper-ceria as one of the very active catalysts for oxidation reactions has been widely investigated in heterogeneous catalysis.
基于第一性原理的电子结构理论计算在材料研究中发挥着日益重要的作用,不仅用于解释和分析实验现象,也日益广泛地应用于新材料的理性设计。
Coordination polymer and metal-organic framework have attracted much research interest,owing to their multifunctional properties such as magnetism,luminescence,gas storage,catalysis,chirality,and sens
Spin-crossover(SCO)complexes were one of the most attractive switchable molecular materials with the potential applications in data storage,molecular switches and sensors.
Chirality is an important category in chemical and biological systems.Chiral coordination polymers play important roles in the fields of asymmetric catalysis,chiral separation,secondharmonic generatio
Two new sandwich-typepolyoxometalatesmodified by open-chain carboxyethyltin groups andtransitionmetals,namely[CN3H6]10[(Sn(CH2CH2COO))2MW(MW9O34)2]·6H2O(M = Co(1),Zn(2)),were synthesized in aqueous so
金属膦酸盐配位聚合物因其结构上的多样性以及在离子交换、吸附材料、质子导电材料、光化学材料和催化材料等领域具有潜在的应用前景,已引起人们的广泛关注和极大的研究热情。
由四个金属离子和四个相互垂直的配体所构成的[2×2]网格化合物在数据存储设备和量子细胞自动机方面显示出广泛的应用价值[1,2]。我们最近开发了多种基于吡唑基吡啶配体的3d 过渡金属离子的[2×2]网格结构。
Photocatalytic hydrogen production,which converts inexhaustible solar energy into hydrogen gas,is one of the most promising green technologies for solving both the energy crisis and issues regarding e
近年来,配合物所涉及的晶体工程和超分子化学领域发展迅速。由于ⅡB 族的金属配合物具有优良的荧光性能和廉价易得的特点成为潜在应用的发光材料。