2. 您的位置
3. 首页
4. 会议论文
5. Synthesis of [60]Fullerene-Fused Lactones via Aryl Carboxylic Acid Group-Directed C-H Bond Activatio

Synthesis of [60]Fullerene-Fused Lactones via Aryl Carboxylic Acid Group-Directed C-H Bond Activatio

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：ghostwh

【摘 要】

：

An efficient Pd-catalyzed aryl carboxylic acid group-directed C-H bond activation with [60]fullerene (C60) was achieved.The obtained [60]fullerolactones could u

【作 者】

：

Dian-Bing Zhou Guan-Wu Wang 

【机 构】

：

DepartmentofChemistry,UniversityofScienceandTechnologyofChina,Hefei,Anhui230026,P.R.China

【出 处】

：

第十届全国物理有机化学学术会议

【发表日期】

：

2013年9期

下载到本地 , 更方便阅读

下载此文 赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

An efficient Pd-catalyzed aryl carboxylic acid group-directed C-H bond activation with [60]fullerene (C60) was achieved.The obtained [60]fullerolactones could undergo an unprecedented rearrangement in the presence of CF3SO3H to afford C60-fused 1-indanones, which could be further reduced to C60-fused indanes.

其他文献

The Unexpected Radical Mechanism for the Reaction between N-Methyl Benzohydroxamic Acid and 2,5-Dich

We have shown recently that the reaction between benzohydroxamic acid (BHA) and 2,5-dichloro-l,4-benzoquinone (DCBQ) could form a relative stable nucleophilic s

会议

Mechanistic Insight into the CO2 Capture by Amidophosphoranes Interplay of the Ring Strain and the T

CO2 capture has attracted increasing attention due to its contribution to global warming and climate change as a greenhouse gas.As an alternative strategy to tr

会议

Degradation of Cellulose into Furan Derivatives in Hot-Compressed Steam

Hot-compressed steam was employed as environmental friendly media for one-pot transformation of cellulose into furan derivatives (5-hydroxymethylfurfural and fu

会议

Reactivity for the Diels-Alder Reaction of Cumulenes A Distortion-Interaction Analysis Along the Rea

Cumulenes, including allene, ketenimine, and ketene, contain characteristic allenic or heteroallenic bonds.They can be employed as dienophiles in Diels-Alder ty

会议

Mechanism of Rhodium-Catalyzed Carbon-Silicon Bond Cleavage for the Synthesis of Silicon Derivatives

Transmetallation and oxidative addition-reductive elimination are key elemental steps for a wild variety of transition-metal-catalyzed processes and also often

会议

FeCl3促进的[60]富勒烯并四氢喹啉的合成

经过近二十多年的发展,许多新的合成策略被应用于新型富勒烯衍生物的合成,为富勒烯化学的发展和应用奠定基础.其中自由基反应尤其是金属盐参与的自由基反应,由于其高效,简捷

会议

Palladium-Catalyzed Synthesis of Sultones via Sulfonic Acid Group-Directed C-H Activation

C60-fused and aromatic sultones could be obtained by the palladium-catalyzed cyclization reactions of arylsulfonic acids with C60[1] and simple arenes,[2] The r

会议

Density functional theory study of the structure-antioxidant activity of polyphenolic deoxybenzoins

Deoxybenzoins (DOBs) are intermediates in the synthesis of isoflavone and found in several plants.As important derivatives of isoflavones, deoxybenzoins exhibit

会议

Copper-Mediated Oxidative Cyclization A Strategy To Construct 3-arylimidazo [1,5-a] pyridines

A copper-mediated oxidative cyclization was demonstrated.Various benzylamine were utilized as substrates to construct 3-arylimidazo[1,5-a]pyridines with picolin

会议

Enzyme-Triggered Release from Mesoporous Silica Nanoparticles Based on Cholin-Sulfonatocalix[4]arene

Most biological processes take place in an aqueous environment;therefore the use of macrocyclic receptors to construct water-soluble supramolecular architecture

会议