Comparision of Cyclic Voltammetry between the bound mono-olefin with nickel bisdithiolene complexes

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：JunKao

【摘要】

：

金属化合物11 可以进行如有机合成中两个单烯之间的[2+2]加成,如下图所示:化合物11 的相关化合物6 可以经历与单烯和双二硫纶镍之间的类似循环伏安图:二聚体还原得一个电子时循环伏安吸收峰很小.估计这两系列金属化合物在循环伏安条件下的第一个电子还原均经历了分子内氧化-还原反应过程.

【作者】

：

汪晓平

【出处】

：

第九届全国无机化学学术会议

【发表日期】

：

2015年7期

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

其他文献

Synthesis and structures of phthalate-containing cadmium(Ⅱ)complexes based on polybenzimidazole Liga

The o-phthalate anion is a well-known versatile ligand,tend to form mono-and polynuclear or polymeric complexes.All these structural and functional versatilities make phthalate ligand an attractive bu

会议

Cadmium(Ⅱ) complexfluorescenceCrystal structurebenzimidazole

Synthesis,structure,and properties of a novel 1D homochiral MnⅢ(5-Brsalen)coordination polymer with

A novel homochiral manganese(Ⅲ)Mn(5-Brsalen)coordination polymer with left-handed helical character by spontaneous resolution on crystallization by using Mn(5-Brsalen)and 4,4-bipyridine has been synth

会议

Spontaneous resolutionChiralityCrystal structureElectrochemistry

Molecular phosphonate manganese-alkali metal clusters

Transition-metal phosphonate complexes have received a lot of attention in recent years primarily because of their potential applications in material chemistry.1-4 Three new Mn(Ⅲ)complexes with unusua

会议

manganese-alkali metal clustersphenylphosphonic acidmagnetic properties

基于3d过渡金属的分子磁体研究

分子基磁体是一类在分子水平上表现出磁性质的配位化合物,主要研究对象包括单分子磁体、单链磁体、单离子磁体、磁有序化合物和自旋交叉化合物。自从第一例单分子磁体Mn12OAc在1990年代被发现以来1,该类化合物独特的磁性质以及在信息存储以及量子计算机的潜在应用引起了化学家、物理学家和材料学家的广泛关注。

会议

3d过渡金属单分子磁体单离子磁体自旋交叉

Syntheses,structures and proton-conducting properties of a new inorganic-organic hybrid material bas

A novel organic–inorganic hybrid,Na[PMo8ⅥMo4ⅤO40Zn4][H2bpz]2(NJNU-L1,H2bpz= 3,3′,5,5′-tetramethyl-4,4′-bipyrazole),based on ε-Zn Keggin units {ε-PMo8ⅥMo4ⅤO40Zn4},have been successfully synthesized und

会议

Ultrastable MOFsPOMsproton-conductivity

Highly Efficient Phosphorescence and Electroluminescence of Cationic Ag6Cu Heteroheptanuclear Cluste

Developing highly emissive organo-metal compounds of earth-abundant metals in place of iridium(Ⅲ)complexes is a promising approach to achieve low-cost electroluminescence.We report herein the use of a

会议

PhosphorescenceElectroluminescenceCopperSilver

Synthesis and Photophysical properties studies of Pt2Ag Heterometallic Alkynyl Complexes based on 2,

A series of Pt2Ag heterotrinuclear alkynyl complexes based on 2,5-bis(diphenylphosphine)thiophene(PTP), trans-[Pt2Ag{μ-PTP}2(C≡C-R)2][ClO4]2 [R=C6H4CF3-4(1),C6H5-4(2),C6H4But-4(3),C6H4OMe-4(4),C6H4Me2

会议

Pt2Ag heterotrinuclear alkynyl ComplexesHeteronuclear ClustersPhosphorescent M

Cyclopalladated complexes containing arylimine and salicylaldimine co-ligands:antibacterial activity

Cyclometallated complexes have attracted considerable interest due to their application in medicine and bioimaging.1 Recently,we reported on synthesis and interaction with bovine serum albumin of cycl

会议

cyclometallated PdSalmon Sperm-DNAantibacterial activity

A Five-Coordinated Iron(Ⅱ)-Iodine Complex Behaves Spin-Crossover and The Research of Reaction with G

Transition metal complexes having d4-d7 electron counts in first-row are typically observed spin crossover.Because of the molecular bistability of spin-crossover,there is enormous interest for applica

会议

Spin-crossoverπ radical aniontransition temperatures

Ionic Compounds with 5-Ferrocenyltetrazolate anion.Synthesis, Structures and Catalytic Effects on Th

The development of new types of ferrocene-based combustion modifiers for composite solid propellants is a continuing work in the field of burning-rate(BR)catalysts.

会议

Ionic ferrocenyl compound1-Ferrocenyltetrazolate anionCombustion catalytic eff

Comparision of Cyclic Voltammetry between the bound mono-olefin with nickel bisdithiolene complexes

与本文相关的学术论文