Effect of Mg, Co co-doping on electrochemical properties of LiFePO4

来源 :2012 Postdoctoral Symposium of China on Materials Science &a | 被引量 : 0次 | 上传用户:zyhhappy
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  LiFePO4 co-doping with Mg and Co ions was synthesized by a solid state reaction method.The structure and electrochemical properties of the prepared LiFe0.99Mg0.005Co0.005PO4 were investigated by X-ray diffraction (XRD), galvanostatic charge-discharge experiment and cyclic voltammograms (CV).The specific discharge capacity of LiFePO4 co-doping with Mg and Co ions reached 147mAhg-1 at 0.1C and 133 mAhg-1 at 1C.The results of CV showed that the reversibility of lithium extraction/insertion in LiFePO4 can be promoted by (Mg2+, Co4+) multiple-ion doping.
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