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5. A 1,2,4-Diazaphospholyl Radical and Its Associated Dimer with Nitrogen-Phosphorus Coupling:Synthesis

A 1,2,4-Diazaphospholyl Radical and Its Associated Dimer with Nitrogen-Phosphorus Coupling:Synthesis

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：gzliuwei2008

【摘 要】

：

The oxidation of 1,2,4-diazaphospholide potassium(K+[2–])with oxidants produced a neutral 1,2,4-diazaphospholyl radical(2(·))which was evidenced by formation of a spin adduct DMPO[2(·)].Radical 2(·)is

【作 者】

：

苏婧 郑文军 

【出 处】

：

第九届全国无机化学学术会议

【发表日期】

：

2015年7期

【关键词】

：

1 2 4-diazaphospholide N-ligand radical five-membered ring radical dimerization 

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　　The oxidation of 1,2,4-diazaphospholide potassium(K+[2–])with oxidants produced a neutral 1,2,4-diazaphospholyl radical(2(·))which was evidenced by formation of a spin adduct DMPO[2(·)].Radical 2(·)is liable to self-associate toward a 2(N)–2(P)dimer through N–P coupling.

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