橄榄石型LiMnPO4正极材料的改性及储能性能的研究

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橄榄石型结构的Li MPO_4(M=Fe、Mn、Ni、Co)因其成本低、环境友好和结构稳定等优点被认为是最有潜力的正极材料,且其家族中的LiFePO_4已经商业化。现在,具有高对锂电势(4.1 V)和高理论能量密度(697 Wh/kg)的Li MnPO_4被认为是下一代锂离子电池正极材料。但LiMnPO_4有其自身的缺陷如电子导电率和锂离子扩散系数都较低、Mn3+的Jahn-Teller效应等,这就限制了其电化学性能,特别是在大倍率下的放电性能。本文主要从导电相炭表面包覆、颗粒尺寸纳米化和形貌控制、
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