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A new MOF {[Cd3(TCOPM)2bpe]-7(H2O)-2DMF}n based on a C-centered tripodal flexible carboxylate ligand and l,2-bis(4-pyridyl)ethane ligand(H3TCOPM = tris(p-carboxyphenyl)methane,bpe = l,2-bis(4-pyridyl) ethane) has been synthesized by the hydrothermal react