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根据几类可逆反应通用的微分动力学方程和热动力学变换方程,本文建立了可逆反应的特征参量研究法.应用该法在两个温度下研究了硝基乙烷分别与氨和Tris反应的热动力学,实验结果验证了可逆反应特征参量法的正确性.
According to the differential kinetic equations and thermodynamic equations which are common to several types of reversible reactions, a method for the characterization of reversible reaction was established in this paper. The reaction of nitroethane with ammonia and Tris Thermokinetics and experimental results verify the correctness of the reversible reaction characteristic parameter method.