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Raw Mg,Si powder were used to fabricate Mg2Si bulk thermoelectric generator by spark plasma sintering (SPS).The optimum parameters to synthesize pure Mg2Si powder were found to be 823 K,0 MPa,10 min with excessive content of 10wt% Mg from the stoichiometric Mg2Si.Mg2Si bulk was synthesized and densified simultaneously at low temperature (823 K) and high pressure (higher than 100 MPa) from the raw powder,but Mg,Si could not react completely,and the sample was not very dense with some microcracks on the surface.Then,Mg,Si powder reacted at 823 K,0 MPa,10 min in SPS chamber to form Mg2Si green compact,again sintered by SPS at 1023 K,20 MPa,5 min.The fabricated sample only contained Mg2Si phase with fully rela-tive density.
Raw Mg, Si powder were used to fabricate Mg2Si bulk thermoelectric generator by spark plasma sintering (SPS). The optimum parameters to synthesize pure Mg2Si powder were found to 823 K, 0 MPa, 10 min with excessive content of 10wt% Mg from the stoichiometric Mg2Si.Mg2Si bulk was synthesized and densified simultaneously at low temperature (823 K) and high pressure (higher than 100 MPa) from the raw powder, but Mg, Si could not react completely, and the sample was not very dense with some microcracks on the surface.Then, Mg, Si powder reacted at 823 K, 0 MPa, 10 min in SPS chamber to form Mg2Si green compact, again sintered by SPS at 1023 K, 20 MPa, 5 min. The fabricated sample only contained Mg2Si phase with fully rela-tive density.