毛细管电泳通常是在以水为溶剂的缓冲溶液中进行的 ,事实上以纯有机溶剂替代水介质同样可以完成特殊样品的电泳分离 ,且存在诸多优点。以所建立的非水毛细管电泳方法为核心 ,总结了该方法中有机溶剂、电解质的选择原则及溶质 -添加剂相互作用模式 ,并综述了它在无机离子、中性物质、有机酸等化合物分离分析中的应用。引用文献 71篇 Capillary electrophoresis is usually carried out in a water-based buffer solution. In fact, the replacement of an aqueous medium with a pure organic solvent can also complete the electrophoresis separation of special samples, and has many advantages. Based on the established non-aqueous capillary electrophoresis method, the selection principles of organic solvents, electrolytes and solute-additive interaction modes in this method were summarized. The separation and analysis of compounds such as inorganic ions, neutral substances and organic acids were reviewed. In the application. 71 references