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A zinc complex, [Zn(iso)_2(H_2O)_4](iso=C_6H_4NO_2~-), was synthesized and characterized by elemental analysis, thermal analysis and IR spectrum studies. The crystal structure of the complex was determined by X-ray diffraction. The crystal crystallizes in the triclinic system, molecular formula ZnC12H16N2O8, Mr=381.64, space group P with a = 6.338(1), b =6.919(1), c=9.277(1), α=96.28(1), β=104.91(1), γ=112.85(1)°, V=352.12(9)?3, Z=1, Dc=1.80g?cm-3 and F(000)=196, μ =1.791mm-1. The crystal structure was solved by direct methods for final R=0.0204 and Rw=0.0542 for 1258 observed reflections with [Fo>4σ(Fo)]. The crystal structure reveals that zinc ion is trans-octahedral with two pyridyl nitrogens and two aque oxygens at the equational positions and two aqua oxygens at the axial positions. The complex forms a three-dimensional network through intermolecular hydrogen bonds.
The crystal structure of the complex was determined by X-ray. The crystal structure of the complex was determined by X-ray diffraction. The crystal crystallizes in the triclinic system, molecular formula ZnC12H16N2O8, Mr = 381.64, space group P with a = 6.338 (1), b = 6.919 (1), c = β = 104.91 (1), γ = 112.85 (1) °, V = 352.12 (9) 3 3, Z = 1, Dc = 1.80g? cm-3 and F (000) = 196, μ = 1.791mm-1 . The crystal structure was solved by direct methods for final R = 0.0204 and Rw = 0.0542 for 1258 observed reflections with [Fo> 4σ (Fo)]. The crystal structure was solved by direct methods for trans-octahedral with two pyridyl nitrogens and two aque oxygens at the equational positions and two aqua oxygens at the axial positions. The complex forms a three-dimensional network through intermolecular hydrogen bonds.