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本文对 J.W.Strojek 等发表的单电位跃扩散控制的光谱电化学关系式进行了讨论。推导了简单电荷转移反应产物在测量波长下无吸收时的光谱电化学关系式,并以光度试剂5-Br-PADAP 的电极还原反应进行了验证,结果满意。
In this paper, we discuss the spectroelectrochemical relationship of single potential jump diffusion controlled by J.W. Strojek et al. The electrochemical relationship of the simple charge-transfer reaction product without absorption at the measurement wavelength was deduced and the result was satisfactory with the electrode reduction reaction of photometric reagent 5-Br-PADAP.