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A model is presented for the simulation of reactive gas-solids flows in large industrial reactors. Circulating fluidized bed (CFB) combustors with several thousands of cubic meters reaction volume are probably the largest reactors of this type. A semi-empirical modeling approach has been chosen to model the three-dimensional concentration distributions of gas and solids components and temperatures inside the combustion chamber of such boilers. Two industrial CFB boilers are investigated in detail: the 105 MWe Duisburg combustor in Germany and the 235 MWe Tur6w combustor in Poland. The semi-empirical model approach is described first. Then the model is used to show how the three-dimensional concentration and temperature fields are formed by the interaction of several local phenomena. Good agreement between simulation and measurements has been achieved.