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本文导出了由电位滴定数据求算弱酸电离常数与混合酸组分浓度的通用算式,按Rosenbrock算法设计程序并处理了某些实验数据,得到良好的结果。与处理同类问题的其它方法相比,本法是方便并可靠的。
In this paper, a general formula for calculating weak acid ionization constants and mixed acid component concentrations from potential titration data is derived. According to Rosenbrock algorithm, some experimental data are processed and some good results are obtained. This Law is convenient and reliable compared to other methods of dealing with similar problems.