以5-[N-乙酸根(4-吡啶基)]四唑为桥联配体,分别与Cu(ClO)2·6H2O和CdCl2的水溶液反应,获得配聚物[Cu(a4-ptz)2·2H2O]n(1)和[{Cd(a4-ptz)·(H2O)2Cl}·H2O]n(2),2个化合物通过元素分析、IR、TGA等表征,并测定了它的晶体结构。结果表明:化合物1是一个二维四方格子结构的配位聚合体,化合物2含有四元环(Cd2Cl2)的一维Z-型聚合链。化合物2在280℃以下热稳定性好,并且不溶于一般溶剂,因此可成为潜在的荧光材料。 The ligands of Cu (a4-ptz) 2 were obtained by the reaction of 5- [N-acetoxy (4-pyridyl)] tetrazole with the aqueous solution of Cu (ClO) 2 · 6H 2 O and CdCl 2 respectively · 2H2O] n (1) and [{Cd (a4-ptz) · (H2O) 2Cl} · H2O] n2 were synthesized and characterized by elemental analysis, IR, TGA and so on. . The results show that compound 1 is a coordination polymer with two-dimensional tetragonal lattice structure and compound 2 contains a one-dimensional Z-type polymer chain with four-membered ring (Cd2Cl2). Compound 2 has good thermal stability below 280 ° C and is insoluble in common solvents and therefore can be a potential fluorescent material.