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One compound with N-(4-pyridylmethyl)imidazole liand, [Co(pyim)2(N3)2]n 1(pyim = N-(4-pyridylmethyl)imidazole), was synthesized and structurally characterized. Compound 1 crystallizes in triclinic, space group P21/c with a = 8.090(3), b = 16.109(3), c = 8