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采用自建动态酯化反应实验装置，通过色谱分析测定了不同催化剂上乙二醇单乙醚醋酸酯合成反应的转化率～时间关系曲线．根据多种催化剂的活性及寿命，筛选出一种较为理想的锆基催化剂．该催化剂在实验条件下，反应２ｈ，转化率达９７％，对目标产物的选择性为１００％．采用程序升温分解（ＴＰＤＥ）及吡啶的程序升温脱附（ＴＰＤ），Ｘ射线衍射（ＸＲＤ）等手段，对新鲜的和重复使用的锆基催化剂进行分析．结果表明，催化剂中的结晶水受到Ｚｒ４＋的诱导作用，使催化剂表面产生较强的Ｂ酸中心，从而对反应具有较高的催化活性；催化剂结晶水不受使用次数的影响，使得催化剂具有稳定的结构，因而具有较长的使用寿命．
The conversion rate ~ time curve of ethylene glycol monoethyl ether acetate synthesis reaction on different catalysts was determined by chromatographic analysis using a self-built dynamic esterification reaction apparatus. According to a variety of catalyst activity and life expectancy, screening out a more ideal zirconium-based catalyst. The catalyst under the experimental conditions, the reaction 2h, the conversion rate of 97%, the selectivity of the target product was 100%. Fresh and reused zirconium-based catalysts were analyzed by temperature programmed desorption (TPD) and pyridine-based temperature programmed desorption (TPD) and X-ray diffraction (XRD). The results show that the crystal water in the catalyst is induced by Zr4 +, which makes the catalyst produce a strong B acid center and thus has a high catalytic activity for the reaction. The crystallization temperature of the catalyst is not affected by the number of uses, which makes the catalyst stable Structure, which has a longer life.