F-T合成是一结构敏感的表面聚合反应,其产物分布比较复杂,许多模型只能近似地描述F-T合成反应的产物分布规律。本文系统总结了近几年用数理统计法对F-T合成产物分布的处理结果,这些方法的共同假设是F-T合成的三类主要产物——烷烃、烯烃和含氧有机物——是经由同一中间体形成的,只是链终止的方式不同。详细介绍了T-W模型和Basini模型,以及对ASF分布的深入分析。 F-T synthesis is a structurally sensitive surface polymerization reaction, the product distribution is more complicated, and many models can only approximate the product distribution of F-T synthesis reaction. In this paper, we summarize the treatment results of FT synthesis products distribution by mathematical statistics in recent years. The common assumption of these methods is that the three main products of FT synthesis - alkanes, alkenes and oxygenated organic compounds - are formed through the same intermediate The only way to terminate the chain is different. The T-W model and the Basini model are introduced in detail, as well as the in-depth analysis of the ASF distribution.