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A new coordination polymer,[Mn(L)(1,4-bdc)] (L=11-fluoro-dipyrido[3,2-a:2,3-c]phenazine,1,4-bdc=benzene-1,4-dicarboxylate),has been synthesized through the hydrothermal method and characterized by elemental analysis,IR and single-crystal X-ray diffraction.It crystalli-zes in triclinic,space group P1 with a=9.7544(9),b=10.8254(10),c=11.5288(10),α=114.1300(10),β=96.6110(10),γ=105.0390(10)°,V=1038.62(16)3,Z=2,C 26 H 13 FMnN 4 O 4,M r=519.34,D c=1.661 g/cm 3,F(000)=526,μ(MoKa)=0.691 mm-1,R=0.0405 and wR=0.0977.The 1,4-bdc dianions link the neighboring Mn(II) atoms to yield a two-dimensional layer structure.The L ligands are attached on both sides of the layer.The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture.
A new coordination polymer, [Mn (L) (1,4-bdc)] (L = 11-fluoro-dipyrido [3,2-a: 2,3-c] , 4-dicarboxylate), has been synthesized through the hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. It crystalli-zes in triclinic, space group P1 with a = 9.7544 (9), b = 10.8254 Α = 114.1300 (10), β = 96.6110 (10), γ = 105.0390 (10) °, V = 1038.62 (16) 3, Z = 2, C 26 H 13 FMnN 4 O 4, M r = 519.34, D c = 1.661 g / cm 3, F (000) = 526, μ (MoKa) = 0.691 mm -1, R = 0.0405 and wR = bdc dianions link the neighboring Mn (II) atoms to yield a two-dimensional layer structure. The L ligands are attached on both sides of the layer. The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture.