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以氯化镍和3-(2-吡啶基)-吡唑为原料,在硝基甲烷中进行反应,常温挥发溶剂得到配合物氯化二水·二[3-(2-吡啶基)-吡唑]合镍(Ⅱ).对目标化合物进行单晶X射线衍射表征,并解析晶体结构,发现其晶体属于单斜晶系,空间群为C2/c,晶胞参数为a=1.605 34(8)nm,b=1.444 14(8)nm,c=0.957 13(6)nm,β=113.045(3)°,V=2.041 9(2)nm3,F(000)=936,Z=4,D=1.483g/cm3,Mr=455.97,μ=1.235mm-1,I>2σ(I)的衍射点有8 470个,S=1.024.
Using nickel chloride and 3- (2-pyridyl) -pyrazole as raw materials, the reaction was carried out in nitromethane and the solvent was evaporated at room temperature to obtain the complex dihydrate bis [3- (2-pyridyl) (Ⅱ) .The single crystal X-ray diffraction (XRD) characterization of the target compound and the crystal structure analysis revealed that the crystal belongs to the monoclinic system with space group C2 / c and the unit cell parameter is a = 1.605 34 (8) ) nm, b = 1.444 14 (8) nm, c = 0.957 13 (6) nm, β = 113.045 (3) °, V = 2.041 9 = 1.483g / cm3, Mr = 455.97, μ = 1.235mm-1, 8 470 for I> 2σ (I), S = 1.024.