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利用水热合成反应合成了[Cu(imi)2]4[(imi)2(Mo8O26)]·H2O配合物.通过元素分析、红外光谱、光电子能谱、循环伏安和差热热重分析对其结构进行表征.用X射线单晶衍射测定了配合物的晶体结构.结果表明,该配合物中每个铜原子由2个咪唑分子配体连接为直线型配位环境,每个γ-{Mo8O26}4-单元与2个咪唑配位,各结构单元通过氢键和π-π堆积作用形成三维超分子结构.
The complex of [Cu (imi) 2] 4 [(imi) 2 (Mo8O26)] · H2O was synthesized by hydrothermal synthesis reaction, and its chemical structure was characterized by elemental analysis, IR spectra, photoelectron spectroscopy, cyclic voltammetry and thermogravimetric analysis Its crystal structure was characterized by X-ray single crystal diffraction.The results showed that each copper atom in the complex consisted of two imidazole molecular ligands connected in linear coordination environment, and each γ- { Mo8O26} 4- units coordinate with two imidazoles, and each structural unit forms a three-dimensional supramolecular structure through hydrogen bond and π-π stacking.