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本文主要介绍几种有机化合物与金属离子形成有吸附性能的络合物产生的所谓“络合吸附波”在催化极谱法中的应用。不讨论氢催化波及一般的络合物吸附波和单纯的吸附波。因为这几种情况在综述论文和专著中已有较好的介绍。 近年来发表的一些论文,认为:络合吸附波的产生与组成金属络合物有无吸附性有关。对络合吸附波的形成,具有以下两种情况:其一是络合剂(或称配位体)必须在电极上有吸附,配位体和金属阳离子形成的络合物可以在电极上吸附。其二,络合剂(或称配位体)可以在电极上有吸附,金属
This article describes the application of several so-called “complexed adsorptive waves” produced by complexes of several organic compounds with metal ions to form adsorptive properties in catalytic polarography. It does not discuss the hydrogen catalysis which affects the general complex adsorption wave and pure adsorption wave. Because these kinds of situations have a good introduction in the review papers and monographs. In recent years, published a number of papers, that: the formation of complex adsorption wave and composition of metal complexes with or without adsorption. The formation of complexed adsorption wave has the following two cases: First, the complexing agent (or ligand) must be adsorbed on the electrode, the ligand and metal cation complex formed on the electrode can be adsorbed . Second, the complexing agent (or ligand) can be adsorbed on the electrode, metal