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5. Studies on Agarofurans VI. The Introduction of Substituents to C-1 and C-2 Positions of Agarofurans

Studies on Agarofurans VI. The Introduction of Substituents to C-1 and C-2 Positions of Agarofurans

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：a65681361

【摘 要】

：

Agarofuranoids with oxygen functions at C-1 and C-2 were synthesized by allylic oxidation.Ketone 2 gave compound 8 and 9 by Grignard reaction.The configuration

【作 者】

：

Wu Yan ZHANG Ji Yu GUO Xiao Ti 

【机 构】

：

Institute of Materia Medica

【出 处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

Agarofuran synthesis 

【基金项目】

：

the National Natural Science Foundation of China

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论文部分内容阅读

Agarofuranoids with oxygen functions at C-1 and C-2 were synthesized by allylic oxidation.Ketone 2 gave compound 8 and 9 by Grignard reaction.The configuration of C-2 in 8 and 9 were identified by the CD spectroscopy of the benzoate 10.

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