氯化锌、三(2-氨基乙基)胺及四氟硼酸钠在甲醇介质中反应,合成单核锌配合物{[(tren)ZnCl]BF4},用IR和1H NMR等手段对该化合物的结构进行表征.单晶x衍射法测得其晶体结构为单斜晶系,空间点群为P2(1)/c,晶体学参数为a=1.068 0(3)nm,b=1.153 2(3)nm,c=1.103 4(3)nm,α=90.00°,β=102.453°,γ=90.00°,V=1.327 0(7)nm3,Dc=1.671 g/cm3,Z=4,F(000)=680,μ=2.083 mm-1. Zinc chloride, tris (2-aminoethyl) amine and sodium tetrafluoroborate in methanol medium to synthesize the mononuclear zinc complex {[(tren) ZnCl] BF4} The crystal structure was monoclinic with the point group P2 (1) / c, the crystallographic parameters were a = 1.068 0 (3) nm and b = 1.153 2 ( 3 = nm, c = 1.103 4 (3) nm, α = 90.00 °, β = 102.453 °, γ = 90.00 °, V = 1.327 0 nm3, Dc = 1.671 g / cm3, 000) = 680, μ = 2.083 mm-1.