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以硫酸钴、邻菲咯啉(phen)和3-羟基-1-金刚烷甲酸(HOC10H14COOH)为原料,合成了配合物[Co(HOC10H14COO)2(H2O)(phen)].H2O;利用元素分析、红外光谱、热重分析对产物进行了表征,采用单晶X射线衍射方法测定了其晶体结构.结果表明,所合成的配合物C34H42N2O8Co属于单斜晶系,空间群C2/c,a=2.69798(7)nm,b=1.14319(3)nm,c=2.29092(6)nm,β=120.498(1)°,V=6.0883(3)nm3,Z=8,Mr=665.63,F(000)=2808,Dc=1.452g.cm-3,μ(Mo-Kα)=0.765mm-1;R1=0.0805,wR2=0.2209.其通过氢键和π-π堆积作用相结合,形成稳定的二维超分子结构.
The complex [Co (HOC10H14COO) 2 (H2O) (phen)]. H2O was synthesized from cobalt sulfate, phenanthroline and HOC10H14COOH. , IR and TG were used to characterize the product.The crystal structure of the product was determined by single crystal X-ray diffraction.The results show that the complex C34H42N2O8Co belongs to monoclinic system with space group C2 / c, a = 2.69798 (7) nm, b = 1.14319 (3) nm, c = 2.29092 (6) nm, β = 120.498 (1) °, V = 6.0883 (3) nm3, Z = 8, Mr = 665.63, F 2808, Dc = 1.452g.cm-3, μ (Mo-Kα) = 0.765mm-1; R1 = 0.0805, wR2 = 0.2209. It combines with π-π stacking to form a stable two- Molecular Structure.