Dynamics of Polymeric Fluids: Part II The Molecular Theory of Die Swell: Correlation of Ultimate Die

来源 :Journal of Materials Science & Technology | 被引量 : 0次 | 上传用户:kingtigerzhang
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A general expression for the correlation of the simple shear (tan(?)) to the molecular parameters and the shear rate (γ) was deduced. It shows that the simple shear (tan(?)) may be resolved into free recoil (recoverable strain) and viscous heating (unrecoverable strain). The magnitudes of the simple shears for recoil (tan(?)E) and (tan(?)V) for viscous heating not only depended on the molecular parameters and the operational variables, but also on the exponential fractions of the recoverable (1-Wγ) and unrecoverable (W-γ) conformations for recoil and viscous heating. Therefore the magnitudes of the simple shears (tan(?)E) for recoil and (tan(?)V) for viscous heating are, respectively, expressed as the partition function to the (1-Wγ)th power and the partition function to the (Wγ)th power. Thus correlations of the total recoil and the ultimately recoverable strains to the molecular parameters [n’, a,η0, GN0 and (1-Wγ)] and the operational variables (γ, (L/D) and tr) were deduced respectively, which show that at very different shear rates (0≤γ≤∞) the polymeric liquids may exhibit a very different viscoelastic behaviors. After introducing the uniform two-dimensional extension, the definition of swelling ratio and the ratio of L to D [De=(L/D)], two expressions for the ultimate die swelling effect and the ultimate extrudate swelling ratio BEVT5 to the molecular parameters [n’, a,η0, GN0 and (1-Wγ)] and the operational variables (γ, (L/D) and tr) were obtained. The two correlation expressions were verified by the experimental data of high-density polyethylene (HDPE) which shows that the two correlation expressions can be used to predict the correlations of the ultimate extrudate swelling behaviors of polymeric liquids to the molecular parameters and the operational variables. A general expression for the correlation of the simple shear (tan (?)) To the molecular parameters and the shear rate (γ) was deduced. It shows that the simple shear (tan (?)) May be resolved into free recoil The magnitudes of the simple shears for recoil (tan (?) E) and (tan (?) V) for viscous heating not only depended on the molecular parameters and the operational variables, but also The magnitudes of the simple shears (tan (?) E) for recoil and (tan (?) V) on the exponential fractions of the recoverable (1-Wγ) and unrecoverable for viscous heating are, respectively, expressed as the partition function to the (1-Wγ) th power and the partition function to the (Wγ) th power. Thus correlations of the total recoil and the final recoverable strains to the molecular parameters [n ’, a, η0, GN0 and (1-Wγ)] and the operational variables (γ, (L / D) and tr) were deduced respectively, which show that at very different shear rates (0 ≦ γ ≦ ∞) the polymeric liquids may exhibit a very different viscoelastic behaviors. After introducing the uniform two-dimensional extension, the definition of swelling ratio and the ratio of L to D [ De = (L / D)], two expressions for the ultimate die swelling effect and the ultimate extrudate swelling ratio BEVT5 to the molecular parameters [n ’, a, η0, GN0 and (1-Wγ)] and the operational variables The two correlation expressions were verified by the experimental data of high-density polyethylene (HDPE) which shows that the two correlation expressions can be used to predict the correlations of the ultimate extrudate swelling behaviors of polymeric liquids to the molecular parameters and the operational variables.
其他文献
氮磷钾硼四元配合肥料是一种新型的多元肥料,它把作物需要的微量元素硼和大量元素结合起来,作为增产的有效手段。硼是作物需要的一种重要元素,它能提高产果率,防止“花而不
麦蜘蛛是取食麦类叶、茎的害螨,在我国主要有麦长腿蜘蛛和麦圆蜘蛛两种。麦长腿蜘蛛主要发生于北纬34~43度地区为害,即长城以南、黄河以北的麦区,以干旱麦田发生普遍而严重。
为了适应我国不同客车市场的需求,安徽安凯汽车股份有限公司于2002年推出了3款新型客车:HFF6120K35型豪华旅游客车、HFF6120K46型公路客车和HFF6110GK50型城市公交车。3款不同
The concept of metamorphic mechanism is put forward according to the change of configurations from one state to another. Different configurations of metamorphi
冯其庸,名迟,字其庸,号宽堂,江苏无锡县前洲镇人,1924年生。1948年毕业于无锡国专。1949年5月,在苏南行署工作,9月任教于无锡市第一女中。1954年8月奉调入京,历任中国人民大
文章应用水液压技术的最新成果 ,研究水液压与气动联动纠偏器的工作原理和控制系统 ,论述了其设计的关键问题 ,并介绍其应用 The article applies the latest achievements
游戏教学是提高教学效率的一种重要方法,体育游戏在体育教学中运用,不仅丰富了体育教学的方式,还会促进体育教学任务的高效完成。同时现在孩子的学业任务繁重,特别是高中阶段
省林业厅在创建文明机关过程中,始终坚持机关为基层服务,为林业生产建设服务的方向,尽自己最大的努力为基层、为群众办实事、办好事,十分注意解决好群众关心的热点、难点和实际困
问:用自来水清洗发动机的方法可取吗?答:很多人在清洗汽车时喜欢顺便用水清洁一下发动机,这种意愿是好的,但却不可取。现在许多汽车都采用铝制的空调散热器、发动机水箱、发
小雪,在每年11月23日或22日。《月令七十二候集解》:“雨下而为寒气所薄,故凝而为雪。小者未盛之辞。”此时中国大部分地区气温逐渐降到0℃以下,但大地尚未过于寒冷,虽开始降