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我们对六次甲基四胺(HMT)加合物的研究早感兴趣。为探讨Sommelet反应机理,我们证实氯化苄与HMT加合物为季胺盐阳离子[(CH_2)_6N_4·CH_2C_6H_5]~+与Cl~-交错堆积组成的离子晶体。晶体中与四配位N联结的C-N键长有明显的增长效应。本文为其平行的工作。实验HMT与溴代丙烯加合物晶体的制备0.8g HMT溶于30 mL 1∶1三氯甲烷-丙酮,滴入0.7mL溴丙烯,待有细小晶体析
We are interested in the study of hexamethylenetetramine (HMT) adducts. To investigate the Sommelet reaction mechanism, we confirmed that the benzyl chloride and HMT adduct are ionic crystals composed of quaternary ammonium salt cation [(CH 2) 6N_4 · CH_2C_6H_5] ~ + and Cl ~ -. Crystal with four coordination N bond C-N bond length has a significant growth effect. This article for its parallel work. Preparation of Experimental HMT and Bromopropene Adduct Crystals 0.8 g of HMT was dissolved in 30 mL of 1: 1 trichloromethane-acetone and dropped into 0.7 mL of bromopropene until fine crystals were obtained