在有机电解合成中采用反应性金属电极近年来已成为这一领域的新分支。这种类型的电极不仅起着在反应基质问进行电子交换的作用,而且也作为反应物参与反应,集电解合成与化学合成于一体。本文介绍借此方法一步合成醇、醛、酮、羧酸等有机化合物的反应,讨论了电极性质及催化剂等因素对反应的影响,介绍有关电解合成装置。 The use of reactive metal electrodes in organic electrolytic synthesis has become a new branch in this area in recent years. Electrodes of this type not only act as an exchange of electrons on the reaction substrate, but also react as a reactant, integrating electrolytic synthesis and chemical synthesis. This article describes the one-step synthesis of alcohols, aldehydes, ketones, carboxylic acids and other organic compounds by this method. The effects of electrode properties and catalysts on the reaction are discussed. The electrolysis synthesis device is introduced.