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本文选择质量为1460μ且金属原子具有三种不同配位环境的四核钴铁簇合物Co3Fe(mp)4(Hmp)(PBu)3(Hmp=2-巯基苯酚,PBu=三了基膦)为研究对象,以快原子轰击软电离方法,研究其质谱断裂行为及其可能的裂解途径。
In this paper, we choose a tetranuclear cobalt-iron cluster Co3Fe (mp) 4 (Hmp) (PBu) 3 (Hmp = 2-mercaptophenol, PBu = trimetyldiphosphine) with a mass of 1460μ and a metal atom with three different coordination states. As the research object, the fast atom bombardment soft ionization method was used to study its mass spectroscopic fracture behavior and its possible cleavage pathways.