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合成了二(3 羧基水杨醛叉)缩1,3 丙二胺(TS)Schiff碱配体的Ni(Ⅱ)单核配合物Na2Ni(TS)·2H2O和Ni(Ⅱ) Fe(Ⅲ)异双核配合物NiFe(TS)Cl·2.5H2O 用元素分析、摩尔电导、IR光谱、UV光谱及差热分析对配合物的组成和结构进行了表征 采用循环伏安法研究了配合物的电化学性质,研究表明:由于第二金属离子的配位增强了内部镍离子的电化学稳定性
Synthesis of Ni (Ⅱ) mononuclear complex Na2Ni (TS) · 2H2O and Ni (Ⅱ) Fe (Ⅲ) with di (3carboxy salicylaldehyde) The composition and structure of the complex were characterized by elemental analysis, molar conductance, IR spectra, UV spectra and differential thermal analysis of NiFe (TS) Cl · 2.5H2O. The electrochemical properties of the complex were studied by cyclic voltammetry , The study shows that: due to the coordination of the second metal ions to enhance the electrochemical stability of the internal nickel ions