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合成了苯并１５－冠－５(Ｂ１５－Ｃ－５)的配合物[Ｎａ(Ｂ１５Ｃ５)·Ｈ２Ｏ]２[Ｚｎ(ＮＣＳ)４],通过元素分析、红外光谱、Ｘ－射线单晶结构衍射对配合物进行了表征．该配合物为单斜晶系,空间群Ｃ２/Ｃ,晶体学结构数据:ａ＝１．６９２ ４(５)ｎｍ,ｂ＝１．２９９ ８(４)ｎｍ,ｃ＝２．１４８ ３(４)ｎｍ,β＝１１２．３５２(６)°,Ｖ＝４．３７１(２)ｎｍ３,Ｚ＝４,Ｄｃ＝１．３８９ｍｇ/ｍ３,Ｆ(０００)＝１８９６,Ｒ１＝０．０６５ ７,ｗＲ２＝０．１７８ ３．结构分析表明:Ｎａ＋与Ｂ１５－Ｃ－５分子中氧原子配位成键,阴离子为[Ｚｎ(ＮＣＳ)４]２－具有四面体构型．两个[Ｎａ(Ｂ１５Ｃ５)·Ｈ２Ｏ」＋配阳离子与一个[Ｚｎ(ＮＣＳ)４]２－配阴离子通过离子键形成中性配合物．
The complex [Na (B15C5) · H2O] 2 [Zn (NCS) 4] of benzo 15-crown-5 (B15-C-5) was synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction The complexes were characterized. The complex is monoclinic, the space group C2 / C, the crystal structure data: a = 1.692 4 (5) nm, b = 1.299 8 (4) nm, c = 2.148 3 (4 ) nm, β = 112.352 (6) °, V = 4.371 (2) nm3, Z = 4, Dc = 1.389 mg / m3, F (000) = 1896, R1 = = 0.178 3. Structural analysis shows that Na + coordinates with the oxygen atom in B15-C-5 molecule and the anion is [Zn (NCS) 4] 2- with tetrahedral configuration. Two [Na (B15C5) · H2O +] cations with a [Zn (NCS) 4] 2- anions form ionic complexes by ionic bonding.