【摘 要】
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Divergently synthesized carbosilane dendrimers generations 1(G1) and 2 (G2) with allyl end groups were bonded onto silica gel.Reactions between the dendrimers a
【机 构】
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Department of Material Science and Engineering,Shandong University,Jinan 250061,China
论文部分内容阅读
Divergently synthesized carbosilane dendrimers generations 1(G1) and 2 (G2) with allyl end groups were bonded onto silica gel.Reactions between the dendrimers and acid-processed silica gel took place,with toluene reflux and organic base as catalyst.Chemically bonded silica gel was characterized by transmission electron microscopy (TEM),infrared (IR),and other methods.The chemically modified silica gels were packed into high-pressure liquid chromatography (HPLC) column and their separation characters were evaluated.G2-bonded silica gel was effective in separating homologous compounds of alcohol, alkyl-substituted benzene,N-substituted benzene,metacrylic acid ester and phthalate.
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