Preparation and Characterization of Microcapsules for Self-healing Materials

来源 :Chemical Research in Chinese Universities | 被引量 : 0次 | 上传用户:lyh041899999
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The urea-formaldehyde(UF) capsules filled with a healing agent, a mixture of epoxy resins(epoxy 711 and E-51) as core material, were produced by means of one step in-situ polymerization. The characteristics of these microcapsules were studied via scanning electron microscopy(SEM), particle size analysis, FTIR and DSC/TGA. The results show that the dispersed and integrated microcapsules of 5 μm in shell thickness were synthesized successfully. The capsules were produced with diameters ranging from 10 to 250 μm via controlling agitation rate. Young’s modulus of the capsule was a little lower than those of the epoxy resins, but the microcapsules having such a shell thickness were robust enough to survive handling during manufacturing self-healing composites. When damage occurred in the epoxy matrix, the crack could rupture the microcapsule to make the repairing agent release. The characteristics of these microcapsules were studied. The urea-formaldehyde (UF) capsules filled with a healing agent, a mixture of epoxy resins (epoxy 711 and E-51) as core material, were produced by means of one step in-situ polymerization. via scanning electron microscopy (SEM), particle size analysis, FTIR and DSC / TGA. The results show that the dispersed and integrated microcapsules of 5 μm in shell thickness were synthesized successfully. The capsules were produced with diameter ranging from 10 to 250 μm via controlling the agitation rate. Young’s modulus of the capsule was a little lower than those of the epoxy resins, but the microcapsules having such a shell thickness were robust enough to survive handling during manufacturing self-healing composites. When damage occurred in the epoxy matrix, the crack could rupture the microcapsule to make the repairing agent release.
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