【摘 要】
：
A convenient and efficient protocol for the synthesis of unnatural N-glycosyl a-amino acids was developed.Condensation of 1,3,4,6-tetra-O-actyl-β-D-glucosamine
【机 构】
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School of Chemical Engineering,Huaihai Institute of Technology,Jiangsu Marine Resources Development
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
A convenient and efficient protocol for the synthesis of unnatural N-glycosyl a-amino acids was developed.Condensation of 1,3,4,6-tetra-O-actyl-β-D-glucosamine hydrochloride,alkenyl boronic acid,and glyoxylic acid was achieved in CH_2C1_2 to give the derivatives of 2-(N-glycosyl)aminobut-3-enoic acid which may find applications in glycobiology research and medicinal chemistry.
A convenient and efficient protocol for the synthesis of unnatural N-glycosyl a-amino acids was developed. Condensation of 1,3,4,6-tetra-O-actyl-β-D-glucosamine hydrochloride, alkenyl boronic acid, and glyoxylic acid was achieved in CH_2C1_2 to give the derivatives of 2- (N-glycosyl) aminobut-3-enoic acid which may find applications in glycobiology research and medicinal chemistry.
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