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Alkylation reaction utilizing alcohols as alkylating reagents through a borrow-hydrogen(BH)or hydrogen autotransfer(HA)s......
Redox homeostasis determines cell fate for both prokaryotes and eukaryotes.In bacteria,redox state depends on aerobic re......
Reversible chain transfer catalyzed polymerization(RTCP)is a practical and efficient process for the precise synthesis o......
Molecular electrochemistry has emerged as an environmentally-friendly platform.While major recent momentum was gained in......
This paper reported the copolymerization results of butadiene and isoprene catalyzed byNdC_6H_6(AlCl_4)_3-AlR_3 system.......
In the range of 76° to 1200C,Dalin and others studied the kinetics on molybdenum-catalyzed epoxi-dation of propylene w......
Intrinsic oxidation kinetics of sulfite catalyzed by peracetic acid under different water quality an
Oxidation of sulfite is an important process in wet flue gas desulfurization.Using highly purified water or distilled wa......
Poly(Imino Ketone)(PIK) is a group of novel high performance polymer material with excellent thermal properties and diss......
Butyl levulinate(BL) is a promising new candidate as diesel fuel and fuel additive. In this study, an efficient process ......
Reactions of [FeL_2(CH_3CN)_2](PF_6)_2(L = N-pyrimid-2-ylimidazolylidene) with N-,P-,O-,and S-donors
Reactions of [FeL2(CH3CN)2]2+(L = N-pyrimid-2-ylimidazolylidene) with various N-,P-,O-,and S-donors were investigated.By......
Recently we reported Pd-catalyzed decarboxylative cross-coupling of cyanoacetate salts with aryl halides and triflates. ......
A theoretical study of the mechanism of the nucleotidyl transfer reaction catalyzed by yeast RNA pol
The mechanism of the nucleotidyl transfer reaction catalyzed by yeast RNA polymerase II has been investigated using mole......
An environmentally benign and highly efficient biomimetic approach for the synthesis of N,N′-diarylsubstituted formamid......
Brφnsted acidic ionic liquid catalyzed highly efficient synthesis of chromeno pyrimidinone derivativ
A series of 8,9-dihydro-2-(2-oxo-2H-chromen-3-yl)-5-aryl-3/f-chromeno[2,3-(flpyrimidine-4,6(5ff,7//)-diones(5a-j) have b......
Reaction mechanism and chemoselectivity of gold(Ⅰ)-catalyzed cycloaddition of 1-(1-alkynyl) cyclopro
The mechanisms of gold(Ⅰ)-catalyzed cycloaddition of 1-(1-alkynyl) cyclopropyl ketones with nucleophiles have been inve......
β-Keto acids are unstable to heat,acids,and bases,and have rarely been employed as carbon nucleophiles for the formatio......
Palladium-catalyzed aerobic transformation has been one of the most challenging topics within organometallics chemistry.......
A Cu(Ⅰ)-catalyzed one-pot tandem reaction of 2-bromobenzyl bromides with 1,3-dicarbonyl compounds leading to 4H-chromen......
A novel diaminophosphine oxide was synthesized and applied as ligand in palladium-catalyzed Suzuki couplings reaction of......
Temporal oscillations of the bromate-4-aminophenol system have been studied in the presence of four different catalysts:......
An account of the total synthesis of(±)-,(+)-heliespirone A and(±)-,(-)-heliespirone C is presented.In the first-gener......
Synthesis of novel chiral tetraaza ligands and their application in enantioselective transfer hydrog
Novel chiral tetraaza ligands(R)-N,N′-bis[2-(piperidin-1-yl)benzylidene]propane-l,2-diamine 6 and(S)-N-[2-(piperidin-l-......
An efficient green protocol for the preparation 3,4,6-trisubstituted 2-pyridone of employing a condensation reaction of ......
An efficient one-pot procedure for the synthesis of multisubstituted xanthone derivatives using Fe-catalyzed reactions o......
Cross double Mannich reaction and tandem cyclization were achieved under iodine catalyzed conditions,yielding a series o......
Polymerization of acrylonitrile catalyzed by lanthanide-sodium alkoxide clusters Ln_2(OCH_2CH_2NMe_2
Polymerization of acrylonitrile was carried out using,for the first time,the lanthanide-sodium alkoxide clusters Ln2(OCH......
An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl......
Schiff base-Cu(Ⅱ) complex is found to be an effective catalyst for the condensation reaction of indole with aldehydes u......
The rapid generation of molecular in a relatively easy manner has made the cycloaddition reaction a powerful tool in the......
An efficient and recyclable iron(III)-containing imidazolium salt catalyst for cross-coupling of ary
1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride, [DIPrim]Cl, was used to produce a novel iron(III)-containing imidazo......
The regioselective acylation of quercetin catalyzed by a novel thermophilic esterase(APE1547) from the archaeon Aeropyru......
A mild,efficient and eco-friendly process for the electrophilic nitration is described using N_2O_5 as a green nitrating......
The iron containing ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate ([C4mim]Cl/FeCl3; = 0.5) proved to be an......
Lewis acidic ionic liquids were used to catalyze the reaction of epoxypropane with POCl_3.Considering the lower cost and......
Three neolignans, (±)-demethylnitidanin(1), herpetol(2) and salvinal(3) were synthesized from methyl 4,5-dihydroxy-3-me......
Development of sequential type iron salt-catalyzed Nazarov/Michael reaction in an ionic liquid solve
Sequential type one pot Nazarov/Michael reaction of pyrrole derivatives has been demonstrated using 5 mol% Fe(ClO4)3·Al......
Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enami
A mild and highly efficient amine-catalyzed,IBX-mediated oxidation of aldehydes to(E) selective α,β-unsaturated aldehy......
A new method for preparation of N-tosylimines by InCl_3-mediated condensation of aldehydes with p-toluenesulfonamide in ......
Acceptorless dehydrogenation(AD) that uses non-toxic reagents and produces no waste is a type of catalytic reactions tow......
Removal of Trace Olefins from Aromatics by Catalytic Alkylation Using 1-Alkyl-3-methylimidazolium Br
Removal of trace olefins from aromatic liquids had been investigated in the presence of various ionic liquids like 1-eth......
Under the high-speed vibration milling conditions,the solvent and catalyst-free azo-Michael addition of chalcone derivat......
The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis(o-formylphenyl)- phenylp......
A fast and convenient C―S bond formation reaction was achieved catalyzed by CuI/L-proline in aqueous two-phase system p......
An efficient and convenient method for preparation of disulfides from thiols using air as oxidant ca
Disulfides have been synthesized by oxidation of thiols using air as oxidant catalyzed by Co-Salophen with high yields,m......
Density functional theory study of the mechanism of the acid-catalyzed decarboxylation of pyrrole-2-
The mechanisms of the acid-catalyzed decarboxylation of pyrrole-2-carboxylic acid and mesitoic acid have been investigat......
Study on the Cracking Mechanism of 1,1,2-Trichloro-1,2,2-trimethyldisilane Catalyzed by Aluminum Chl
The cracking mechanism of 1,1,2-trichloro-l,2,2-trimethyldisilane catalyzed by aluminum chloride is investigated by DFT ......
Porous polymer supported palladium catalyst for cross coupling reactions with high activity and recy
Porous polymer supported palladium catalyst for cross coupling reactions with high activity has been successfully prepar......
Hollow titanium silicalite (HTS) molecular sieve has been synthesized, and information on its structure, physico-chemica......
A highly efficient catalytic system composed of a simple and commercially available chiral primary diamine(1R,2R)-cycloh......