模板剂碳链长度MCM-41晶体结构的影响

来源 :中国化学工程学报 | 被引量 : 0次 | 上传用户:boylsc
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The mesoporous molecular sieve (MCM)-41 using ionic liquid as template has been prepared.The typical template of ionic liquid Was[C16mim]X.In thiS article,the use of 1-alkyl-3-methylimidazolium([Cnmim]Br,where n=12.14,16,18,20)salts as templates in the synthesis of MCM-41 is reported.The results showed that the synthesized MCM-41 had uniforlTl pore diameter,high surface area and stable framework.The largest surface area of MCM-41 Was the one prepared with [C14mim]Br as template.When using[C18min]Br as template,the narrowest pore distribution sample Was obtained and the effect of surface tension of template solution to MCM-41 Was first discussed.
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