【摘 要】
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A simple and versatile method for the synthesis of 1,5-benzodiazepines from o-phenylenediamine and ketones in the presence of solvents and under solvent-free co
【机 构】
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Department of Chemistry,Catalysis Research Laboratory,St.Joseph's College Research Centre,Department
论文部分内容阅读
A simple and versatile method for the synthesis of 1,5-benzodiazepines from o-phenylenediamine and ketones in the presence of solvents and under solvent-free conditions that used an amorphous mesoporous iron aluminophosphate as catalyst was developed.High yields with excellent selectivity were obtained with a wide variety of ketones under mild reaction conditions.The catalyst had the advantages of ease of preparation,ease of handling,simple recovery,reusability,non toxicity,and being inexpensive.
A simple and versatile method for the synthesis of 1,5-benzodiazepines from o-phenylenediamine and ketones in the presence of solvents and under solvent-free conditions that used an amorphous mesoporous iron aluminophosphate as catalyst was developed. High yields with the excellent selectivity were obtained with a wide variety of ketones under mild reaction conditions. catalyst has the advantages of ease of preparation, ease of handling, simple recovery, reusability, non toxicity, and being inexpensive.
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