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A new 3D complex,[Co(L)(bpe)0.5(H2O)2]n(1,H2 L = 5-iodo-benzene-1,3-dioxyacetic acid,bpe = 1,2-bis(4-pyridyl)ethylene),has been hydrothermally synthesized and structurally characterized by elemental analysis,IR and X-ray diffraction.It is formulated as C1