,Dynamics of Aggregate Growth Through Monomer Birth and Death

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We investigate the kinetic behaviour of the growth of aggregates through monomer birth and death and propose a simple model with the rate keels K(k) ∝ ku and K′(k) ∝ kv at which the aggregate Ak of size k respectively yields and loses a monomer. For the symmetrical system with K(k) = K′(k), the aggregate size distribution approaches the conventional scaling form in the case of u < 2, while the system may undergo a gelation-like transition in the u > 2 case. Moreover, the typical aggregate size S(t) grows as t1/(2-u) in the u < 2 case and increases exponentially with time in the u = 2 case. We also investigate several solvable systems with asymmetrical rate keels and find that the scaling of the aggregate size distribution may break down in most cases.
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