论文部分内容阅读
A new cadmium complex Cd(phen)3·(ClO4)2·(α-FRA)·(H2O)3 was prepared by self-assembly of α-furoic acid=1,10-phenanthroline(phen)=and cadmium perchlorate.It crystal-lizes in the monoclinic system=space group P21/n=with a=1.28130(15)=b=2.5957(3)=c=1.35449(16) nm=β=109.395(2)o=V=4.2492(9) nm3=Dc=1.491 g/cm3=Z=4=F(000)=1926=GOOF=1.023=the final R=0.0729 and wR=0.2086.The crystal structure analysis indicates that the cadmium ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules=giving a distorted octahedral coordination geometry.The cyclic voltametric behavior of the com-plex was also investigated.
A new cadmium complex Cd (phen) 3 · (ClO4) 2 · (α-FRA) · (H2O) 3 was prepared by self-assembly of α-furoic acid = 1,10-phenanthroline (phen) = and cadmium perchlorate. It crystal-lizes in the monoclinic system = space group P21 / n = with a = 1.28130 (15) = b = 2.5957 (3) = c = 1.35449 nm = β = 109.395 (2) o = V = 4.2492 9) nm3 = Dc = 1.491 g / cm3 = Z = 4 = F (000) = 1926 = GOOF = 1.023 = the final R = 0.0729 and wR = 0.2086 The crystal structure analysis indicates that the cadmium ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules = giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the com-plex was also investigated.